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  1. Machine learning informed rational design of high entropy double perovskite oxide universal air/steam electrodes for solid oxide electrochemical cells

    Due to their high efficiency and versatility, solid oxide electrochemical cells (SOCs) are poised to play a significant role in future energy conversion and storage applications. In recent years, SOCs have bifurcated into two distinct categories: traditional oxygen-ion conducting SOCs that typically operate from ∼650—850 °C and the more recent proton-conducting ceramic (PCC) SOCs that typically operate from ∼400—650 °C. Current performance and lifetime of both oxygen-ion conducting SOCs and PCCs is primarily limited by the air/steam electrode, which facilitates the oxygen reduction reaction (ORR) during fuel cell operation and must also facilitate the oxygen evolution reaction (OER) during electrolysismore » operation. Here, we present a newly designed high-entropy double perovskite oxide suitable as a universal ORR/OER electrode for both oxygen-ion conducting SOCs and PCCs. Machine learning methods are applied to identify chemical descriptors for highly catalytic high-entropy double perovskite oxides (AA’B2O6) across a large compositional space. Based on the machine-learning guidance, we ultimately converge on Ba0.9Cs0.1(Ca0.2Gd0.2La0.2Pr0.2Sr0.2)Co1.5Fe0.5O6 (CsBaHEO) as a universal air/steam electrode. Structure stabilization is accomplished by an equimolar five-cation high-entropy composition on the A’-site, while cesium substitution on the A-site enhances the electrical conductivity and leads to a higher oxygen vacancy concentration. This material exhibits versatility and high performance in reversible oxygen-ion SOCs, reversible PCCs, and also large-scale tubular PCCs. For example, the CsBaHEO-based PCC reaches 1018 mW∙cm−2 at 600°C, while a large-scale tubular PCC using CsBaHEO for electrolysis achieves a hydrogen production rate of 21.314 ML∙min−1 at 600 °C.« less
  2. Modeling transient edge plasma transport with dynamic recycling

    The work presents numerical simulation studies of the role that dynamic plasma recycling on the main wall and divertor target surfaces plays in transient edge plasma transport phenomena, such as edge localized modes (ELMs). The studies are performed by coupling the edge plasma transport code UEDGE [Rognlien et al., J. Nucl. Mater. 196–198, 347 (1992)] and the wall reaction–diffusion transport code FACE [Smirnov et al., Fusion Sci. Technol. 71, 75 (2017)]. The two-dimensional, time-dependent, two-way coupling of the codes, in a realistic tokamak geometry, is accomplished using the Integrated Plasma Simulator framework [Elwasif et al., in 18th Euromicro Conference onmore » Parallel, Distributed and Network-Based Processing (PDP 2010), Pisa, Italy (IEEE, 2010), pp. 419–427] for all modeled material plasma boundaries. The simulations show that dynamic plasma recycling has substantially different characteristics on the main wall and on the divertor plates. It is demonstrated that during an ELM cycle the outer wall can dynamically absorb and release a number of particles comparable to that expelled by the ELM from the core plasma, by far exceeding the dynamic retention capacity of the divertor surfaces. The resulting evolution of the edge and divertor plasma conditions during an ELM cycle is analyzed.« less
  3. Comparison of Four Cell Topologies for 1.2-kV Accumulation- and Inversion-Channel 4H-SiC MOSFETs: Analysis and Experimental Results

    The electrical characteristics of 1.2-kV-rated 4H-SiC accumulation (Acc) and inversion (Inv) channel MOSFETs with linear, square, hexagonal, and octagonal cell topologies fabricated using the same design rules and process flow in a 6-in foundry are compared for the first time. TCAD numerical simulations have been conducted to analyze the structures. For all the cell topologies, it was found that the Acc MOSFETs have lower specific ON-resistance (RON,sp) than the Inv counterparts due to higher channel mobility resulting in 1.3-2.0× smaller high-frequency figure-of-merit (HF-FOM[RON × Qgd]), where Qgd is the gate-to-drain charge. It is observed that the square and hexagonal cellmore » topologies with the same structural dimensions show similar electrical performance. Here, when compared with the standard linear cell topology: 1) the hexagonal cell topology has 1.15× better specific ON-resistance and 1.12× worse HF-FOM[RON × Qgd] and 2) the octagonal cell topology has 1.5× worse specific ON-resistance and 1.4× better HF-FOM[RON × Qgd]. In addition, the octagonal cell topology has a much superior figure-of-merit (FOM[Ciss/Crss]), where Ciss is the input capacitance and Cgd is the reverse transfer capacitance.« less
  4. Supercapacitance and oxygen reduction characteristics of sulfur self-doped micro/mesoporous bio-carbon derived from lignin

    The growing global concerns about the increased fossil fuel consumption and related environmental issues have motived scientists to find new, green and sustainable energy resources and technologies. In this work, byproduct lignin biomass was successfully converted into sulfur self-doped carbon via in-situ hydrothermal carbonization followed by thermal annealing. The sulfur surface content in the as-prepared porous carbon is up to 3.2 wt % as indicated by the XPS measurements. Beyond the traditional synthesis methods which employ KOH or ZnCl2 treatment to activate the carbon surface, the developed synthesis strategy doesn't include such separate activation step. Activation of the as-prepared porousmore » carbons has been conducted in-situ via a calcium ions during the synthesis process. The resulting materials displayed high BET surface areas up to 660 m2 g-1 along with micro/meso porosity and graphitic/amorphous carbon structure. The as-prepared sulfur self-doped electrode materials displayed high electrochemical activity for supercapacitor applications. The sulfur-doped carbon SC-850 electrode exhibited capacitance of 225 F/g at a current density of 0.5 A/g, and high durability where the electrode capacitance did not change over 10,000 cycles at harsh conditions. Additionally, the as-prepared sulfur-doped carbons are promising catalysts for oxygen reduction reaction with 3.4 electrons transferred per molecule at 0.8 V, which approaches the optimum 4-electron pathway.« less
  5. A path to stable low-torque plasma operation in ITER with test blanket modules

    New experiments in the low-torque ITER Q = 10 scenario on DIII-D demonstrate that n = 1 magnetic fields from a single row of ex-vessel control coils enable operation at ITER performance metrics in the presence of applied non-axisymmetric magnetic fields from a test blanket module (TBM) mock-up coil. With n = 1 compensation, operation below the ITER-equivalent injected torque is successful at three times the ITER equivalent toroidal magnetic field ripple for a pair of TBMs in one equatorial port, whereas the uncompensated TBM field leads to rotation collapse, loss of H-mode and plasma current disruption. In companion experimentsmore » at high plasma beta, where the n = 1 plasma response is enhanced, uncorrected TBM fields degrade energy confinement and the plasma angular momentum while increasing fast ion losses; however, disruptions are not routinely encountered owing to increased levels of injected neutral beam torque. In this regime, n = 1 field compensation leads to recovery of a dominant fraction of the TBM-induced plasma pressure and rotation degradation, and an 80% reduction in the heat load to the first wall. These results show that the n = 1 plasma response plays a dominant role in determining plasma stability, and that n = 1 field compensation alone not only recovers most of the impact on plasma performance of the TBM, but also protects the first wall from potentially damaging heat flux. Despite these benefits, plasma rotation braking from the TBM fields cannot be fully recovered using standard error field control. Lastly, given the uncertainty in extrapolation of these results to the ITER configuration, it is prudent to design the TBMs with as low a ferromagnetic mass as possible without jeopardizing the TBM mission.« less

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